Chlorido[2,2′-[1,2-phenylenebis(nitrilomethanylylidyne)]diphenolato-κ4 O,N,N′,O′]manganese(III) methanol monosolvate
نویسندگان
چکیده
In the title complex, [Mn(C20H14N2O2)Cl]·CH3OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525 (4) Å out of the square basal N2O2 least-squares plane. The complex mol-ecule is hydrogen bonded to the methanol solvent mol-ecule.
منابع مشابه
The cocrystal aquachlorido{6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}manganese(III)–chlorido{6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}(methanol-κO)manganese(III) (1/1)
The asymmetric unit of the title complex, [Mn(C(28)H(30)N(2)O(2))Cl(H(2)O)][Mn(C(28)H(30)N(2)O(2))Cl(CH(3)OH)], contains two discrete Mn(III) complexes of a Schiff base ligand, with an N(2)O(2) donor set. Both Mn(III) centers are in a distorted octa-hedral geometry with the N(2)O(2) donor atoms of the tetra-dentate Schiff base dianion in the equatorial plane. The axial positions in the coordina...
متن کاملChlorido{4,4′-dichloro-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}(methanol-κO)manganese(III)
In the title complex, [Mn(C(20)H(12)Cl(2)N(2)O(2))Cl(CH(3)OH)], the Mn(III) atom is in an octa-hedral coordination geometry with the N(2)O(2) atoms of the doubly-deprotonated Schiff base forming a square around it. The chloride ion and the O atom of the methanol mol-ecule occupy the other two positions of the octa-hedron. The dihedral angle between the two outer phenolate rings of the tetra-den...
متن کامل{2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ4 O,N,N′,O′}(methanol-κO)zinc
In the title complex, [Zn(C18H10N4O2)(CH4O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2-)) and a methanol mol-ecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2-), in a nearly planar configuration, and one methanol O atom, forming a slightly distorted square-pyramidal geometry. The methanol mol...
متن کاملChlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}manganese(III) monohydrate
In the title complex, [Mn(C(22)H(18)N(2)O(2))Cl]·H(2)O, the Mn(III) center is in a distorted square-pyramidal configuration, with the N(2)O(2) dianionic tetra-dentate Schiff base ligand in the basal plane and the chloride ion in the apical position. The dihedral angle between the two outer phenolate rings of the tetra-dentate ligand is 8.25 (8)°. The central benzene ring makes dihedral angles o...
متن کاملChlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}manganese(III)
In the title complex, [Mn(C(22)H(18)N(2)O(4))Cl], the Mn(III) centre is in a distorted square-pyramidal configuration, with the basal plane formed by the N(2)O(2) donors of the tetra-dentate Schiff base dianion; the two phenolate O atoms and the two imine N atoms are each mutually cis. The chloride ion occupies the apical position. The dihedral angle between the two outer phenolate rings of the...
متن کامل